Hydrogenation of carbon dioxide to methanol using a homogeneous ruthenium–Triphos catalyst: from mechanistic investigations to multiphase catalysis

The hydrogenation of CO(2) to methanol can be achieved using a single molecular organometallic catalyst. Whereas homogeneous catalysts were previously believed to allow the hydrogenation only via formate esters as stable intermediates, the present mechanistic study demonstrates that the multistep tr...

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Veröffentlicht in:Chem Sci
Hauptverfasser: Wesselbaum, Sebastian, Moha, Verena, Meuresch, Markus, Brosinski, Sandra, Thenert, Katharina M., Kothe, Jens, Stein, Thorsten vom, Englert, Ulli, Hölscher, Markus, Klankermayer, Jürgen, Leitner, Walter
Format: Artigo
Sprache:Inglês
Veröffentlicht: Royal Society of Chemistry 2015
Schlagworte:
Chemistry
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6085670/
https://ncbi.nlm.nih.gov/pubmed/30154993
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02087a
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