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Mechanistic Studies on Tryptophan Lyase (NosL): Identification of Cyanide as a Reaction Product
Tryptophan lyase (NosL) catalyzes the formation of 3-methylindole-2-carboxylic acid and 3-methylindole from L-tryptophan. In this paper, we provide evidence supporting a formate radical intermediate and demonstrate that cyanide is a byproduct of the NosL-catalyzed reaction with L-tryptophan. These e...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6078386/ https://ncbi.nlm.nih.gov/pubmed/29232124 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b09000 |
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