Highly Stereoselective Synthesis of Tetrasubstituted Acyclic All-carbon Olefins via Enol Tosylation and Suzuki–Miyaura Coupling

A highly stereocontrolled synthesis of tetrasubstituted acyclic all-carbon olefins has been developed via a stereoselective enolization and tosylate formation, followed by a palladium-catalyzed Suzuki–Miyaura cross-coupling of the tosylates and pinacol boronic esters in the presence of Pd(OAc)(2)/Ru...

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Publicado en:J Am Chem Soc
Main Authors: Li, Beryl X., Le, Diane N., Mack, Kyle A., McClory, Andrew, Lim, Ngiap-Kie, Cravillion, Theresa, Savage, Scott, Han, Chong, Collum, David B., Zhang, Haiming, Gosselin, Francis
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6059653/
https://ncbi.nlm.nih.gov/pubmed/28715208
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b05071
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