Spontaneous Assembly of an Organic–Inorganic Nucleic Acid Z‐DNA Double‐Helix Structure

Herein, we report a hybrid polyoxometalate organic–inorganic compound, Na(2)[(HGMP)(2)Mo(5)O(15)]⋅7 H(2)O (1; where GMP=guanosine monophosphate), which spontaneously assembles into a structure with dimensions that are strikingly similar to those of the naturally occurring left‐handed Z‐form of DNA....

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Kulikov, Vladislav, Johnson, Naomi A. B., Surman, Andrew J., Hutin, Marie, Kelly, Sharon M., Hezwani, Mohammed, Long, De‐Liang, Meyer, Gerd, Cronin, Leroy
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6057607/
https://ncbi.nlm.nih.gov/pubmed/27900812
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201606658
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