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Inhibition of hydrocarbon autoxidation by nitroxide-catalyzed cross-dismutation of hydroperoxyl and alkylperoxyl radicals

Nitroxides are putative intermediates in the accepted reaction mechanisms of the diarylamine and hindered amine antioxidants that are universally added to preserve synthetic and natural hydrocarbon-based materials. New methodology which enables monitoring of hydrocarbon autoxidations at low rates of...

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Опубликовано в: :Chem Sci
Главные авторы: Harrison, Kareem A., Haidasz, Evan A., Griesser, Markus, Pratt, Derek A.
Формат: Artigo
Язык:Inglês
Опубликовано: Royal Society of Chemistry 2018
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC6053651/
https://ncbi.nlm.nih.gov/pubmed/30079220
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01575a
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