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Formal Giese addition of C(sp(3))–H nucleophiles enabled by visible light mediated Ni catalysis of triplet enone diradicals
An unprecedented utilization of triplet excited enones in Ni-catalysis enabled a formal Giese addition of C(sp(3))–H nucleophiles. This mechanism-based approach has greatly widened the reaction scope, allowing the synthesis of previously inaccessible structures. In this process, the enone diradical...
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| Publicado no: | Chem Sci |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6050596/ https://ncbi.nlm.nih.gov/pubmed/30079192 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01827h |
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