Efficient cleavage of aryl ether C–O linkages by Rh–Ni and Ru–Ni nanoscale catalysts operating in water

Bimetallic Ru–Ni and Rh–Ni nanocatalysts coated with a phase transfer agent efficiently cleave aryl ether C–O linkages in water in the presence of hydrogen. For dimeric substrates with weaker C–O linkages, i.e. α-O-4 and β-O-4 bonds, low loadings of the precious metal (Rh or Ru) in the nanocatalysts...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Bulut, Safak, Siankevich, Sviatlana, van Muyden, Antoine P., Alexander, Duncan T. L., Savoglidis, Georgios, Zhang, Jiaguang, Hatzimanikatis, Vassily, Yan, Ning, Dyson, Paul J.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6049526/
https://ncbi.nlm.nih.gov/pubmed/30061984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00742j
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