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Vibrational coherence transfer in the ultrafast intersystem crossing of a diplatinum complex in solution
We investigate the ultrafast transient absorption response of tetrakis(μ-pyrophosphito)diplatinate(II), [Pt(2)(μ-P(2)O(5)H(2))(4)](4−) [hereafter abbreviated Pt(pop)], in acetonitrile upon excitation of its lowest singlet (1)A(2u) state. Compared with previously reported solvents [van der Veen RM, C...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6048523/ https://ncbi.nlm.nih.gov/pubmed/29941568 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1719899115 |
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