Vibrational coherence transfer in the ultrafast intersystem crossing of a diplatinum complex in solution

We investigate the ultrafast transient absorption response of tetrakis(μ-pyrophosphito)diplatinate(II), [Pt(2)(μ-P(2)O(5)H(2))(4)](4−) [hereafter abbreviated Pt(pop)], in acetonitrile upon excitation of its lowest singlet (1)A(2u) state. Compared with previously reported solvents [van der Veen RM, C...

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Publicat a:Proc Natl Acad Sci U S A
Autors principals: Monni, Roberto, Capano, Gloria, Auböck, Gerald, Gray, Harry B., Vlček, Antonín, Tavernelli, Ivano, Chergui, Majed
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 2018
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PNAS Plus
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6048523/
https://ncbi.nlm.nih.gov/pubmed/29941568
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1719899115
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