A diuranium carbide cluster stabilized inside a C(80) fullerene cage

Unsupported non-bridged uranium–carbon double bonds have long been sought after in actinide chemistry as fundamental synthetic targets in the study of actinide-ligand multiple bonding. Here we report that, utilizing I(h)(7)-C(80) fullerenes as nanocontainers, a diuranium carbide cluster, U=C=U, has...

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Publicado no:Nat Commun
Main Authors: Zhang, Xingxing, Li, Wanlu, Feng, Lai, Chen, Xin, Hansen, Andreas, Grimme, Stefan, Fortier, Skye, Sergentu, Dumitru-Claudiu, Duignan, Thomas J., Autschbach, Jochen, Wang, Shuao, Wang, Yaofeng, Velkos, Giorgios, Popov, Alexey A., Aghdassi, Nabi, Duhm, Steffen, Li, Xiaohong, Li, Jun, Echegoyen, Luis, Schwarz, W. H. Eugen, Chen, Ning
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2018
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6048043/
https://ncbi.nlm.nih.gov/pubmed/30013067
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-018-05210-8
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