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Directed, Palladium(II)-Catalyzed Intermolecular Aminohydroxylation of Alkenes Using a Mild Oxidation System
A palladium(II)-catalyzed β,γ-aminohydroxylation reaction of non-conjugated alkenyl carbonyl compounds has been developed. This reaction utilizes a cleavable bidentate directing group to achieve regioselective aminopalladation. The resulting chelation-stabilized alkylpalladium(II) intermediate is th...
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| 發表在: | Org Lett |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2018
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6039249/ https://ncbi.nlm.nih.gov/pubmed/29888604 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b01440 |
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