Enantiodivergent Synthesis of Allenes by Point‐to‐Axial Chirality Transfer

An enantiodivergent method for the synthesis of multiply substituted allenes is described. Highly enantioenriched, point‐chiral boronic esters were synthesized by homologation of α‐seleno alkenyl boronic esters with lithiated carbamates and eliminated to form axially chiral allene products. By emplo...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Armstrong, Roly J., Nandakumar, Meganathan, Dias, Rafael M. P., Noble, Adam, Myers, Eddie L., Aggarwal, Varinder K.
Materialtyp: Artigo
Språk:Inglês
Publicerad: John Wiley and Sons Inc. 2018
Ämnen:
Communications
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6033179/
https://ncbi.nlm.nih.gov/pubmed/29719111
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201804446
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