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Intramolecular multi-bond strain: the unrecognized side of the dichotomy of conjugated systems
Electron conjugation stabilizes unsaturated systems and diminishes the differences among bond distances. Experimentally, Kistiakowsky and coworkers first measured and noticed the difference between the hydrogenation heats of carbon–carbon double bonds in conjugated systems. For instance, the hydroge...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Royal Society of Chemistry
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6024246/ https://ncbi.nlm.nih.gov/pubmed/30034728 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00454g |
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