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Preparation of an ion with the highest calculated proton affinity: ortho-diethynylbenzene dianion

Owing to the increased proton affinity that results from additional negative charges, multiply-charged anions have been proposed as one route to prepare and access a range of new and powerful “superbases”. Paradoxically, while the additional electrons in polyanions increase basicity they serve to di...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Poad, Berwyck L. J., Reed, Nicholas D., Hansen, Christopher S., Trevitt, Adam J., Blanksby, Stephen J., Mackay, Emily G., Sherburn, Michael S., Chan, Bun, Radom, Leo
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6024202/
https://ncbi.nlm.nih.gov/pubmed/30034765
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01726f
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