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Metal-free disproportionation of formic acid mediated by organoboranes

In the presence of dialkylboranes, formic acid can be converted to formaldehyde and methanol derivatives without the need for an external reductant. This reactivity, in which formates serve as the sole carbon and hydride sources, represents the first example of the disproportionation of formate anio...

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Bibliografski detalji
Izdano u:Chem Sci
Glavni autori: Chauvier, Clément, Thuéry, Pierre, Cantat, Thibault
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2016
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6021958/
https://ncbi.nlm.nih.gov/pubmed/30034706
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01410k
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