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Metal-free disproportionation of formic acid mediated by organoboranes
In the presence of dialkylboranes, formic acid can be converted to formaldehyde and methanol derivatives without the need for an external reductant. This reactivity, in which formates serve as the sole carbon and hydride sources, represents the first example of the disproportionation of formate anio...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6021958/ https://ncbi.nlm.nih.gov/pubmed/30034706 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01410k |
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