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Traveling two diverging roads, cytochrome-P450 catalyzed demethylation and γ-lactone formation in bacterial gibberellin biosynthesis
Biosynthesis of the gibberellin plant hormones evolved independently in plants and microbes, but the pathways proceed via similar transformations. The combined demethylation and γ-lactone ring forming transformation is of significant mechanistic interest, yet remains opaque. The relevant CYP112 from...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6020689/ https://ncbi.nlm.nih.gov/pubmed/29517843 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201713403 |
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