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The Si(2)H radical supported by two N-heterocyclic carbenes
Cyclic voltammetric studies of the hydridodisilicon(0,II) borate [(Idipp)(H)Si(II)[double bond, length as m-dash]Si(0)(Idipp)][B(Ar(F))(4)] (1H[B(Ar(F))(4)], Idipp = C[N(C(6)H(3)-2,6-iPr(2))CH](2), Ar(F) = C(6)H(3)-3,5-(CF(3))(2)) reveal a reversible one-electron reduction at a low redox potential (...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6018643/ https://ncbi.nlm.nih.gov/pubmed/30155147 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc01569g |
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