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Recent advances in N-heterocyclic carbene-based radical catalysis

In nature, a number of enzymes use thiamine diphosphate as a coenzyme to catalyze the pyruvate decarboxylation. The resultant enamine, a so-called “Breslow intermediate,” is known to perform single electron transfer to various electron acceptors. Inspired by this enzymatic catalysis, N-heterocyclic...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Ishii, Takuya, Nagao, Kazunori, Ohmiya, Hirohisa
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8159350/
https://ncbi.nlm.nih.gov/pubmed/34094077
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc01538e
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