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Calixarenes as High Temperature Matrices for Thermally Activated Delayed Fluorescence: C(70) in Dihomooxacalix[4]arene

Thermally activated delayed fluorescence (TADF) of (12)C(70) and (13)C(70) was observed up to 140 °C in a p-tert-butyldihomooxacalix[4]arene solid matrix, a temperature range significantly higher than that of previous TADF quantitative studies. An effective singlet–triplet energy gap of 29 kJ/mol an...

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Palmeira, Tiago, Miranda, Alexandre S., Marcos, Paula M., Berberan-Santos, Mário N.
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6017425/
https://ncbi.nlm.nih.gov/pubmed/29498664
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules23030558
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