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A N,N′-dioxide/Mg(OTf)(2) complex catalyzed enantioselective α-addition of isocyanides to alkylidene malonates
A highly efficient catalytic asymmetric α-addition of isocyanides to alkylidene malonates was accomplished. The process was based on the utilization of a chiral N,N′-dioxide/Mg(II) catalyst, delivering a variety of 2-alkyl-5-aminooxazoles in up to 99% yield and 96% ee under mild reaction conditions....
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6016448/ https://ncbi.nlm.nih.gov/pubmed/30155124 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00689b |
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