Regioselective phenylene-fusion reactions of Ni(ii)-porphyrins controlled by an electron-withdrawing meso-substituent

Oxidation of 10,15,20-triaryl Ni(ii)-porphyrins bearing an electron-withdrawing substituent at the 5-position with DDQ and FeCl(3) gave 10,12- and 18,20-doubly phenylene-fused Ni(ii)-porphyrins regioselectively. A doubly phenylene-fused meso-chloro porphyrin thus prepared was reductively coupled to...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Fukui, Norihito, Lee, Seung-Kyu, Kato, Kenichi, Shimizu, Daiki, Tanaka, Takayuki, Lee, Sangsu, Yorimitsu, Hideki, Kim, Dongho, Osuka, Atsuhiro
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6013929/
https://ncbi.nlm.nih.gov/pubmed/30155049
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04748j
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