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(1)H Dynamic Nuclear Polarization Based on an Endogenous Radical

We demonstrate a 15-fold enhancement of solid-state NMR signals via dynamic nuclear polarization (DNP) based on a stable, naturally occurring radical in a protein: the flavin mononucleotide (FMN) semiquinone of flavodoxin. The linewidth of flavodoxin’s EPR signal suggests that the dominant DNP mecha...

詳細記述

保存先:
書誌詳細
出版年:J Phys Chem B
主要な著者: Maly, Thorsten, Cui, Dongtao, Griffin, Robert G., Miller, Anne-Frances
フォーマット: Artigo
言語:Inglês
出版事項: 2012
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6010065/
https://ncbi.nlm.nih.gov/pubmed/22472179
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp300539j
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