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(1)H Dynamic Nuclear Polarization Based on an Endogenous Radical
We demonstrate a 15-fold enhancement of solid-state NMR signals via dynamic nuclear polarization (DNP) based on a stable, naturally occurring radical in a protein: the flavin mononucleotide (FMN) semiquinone of flavodoxin. The linewidth of flavodoxin’s EPR signal suggests that the dominant DNP mecha...
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| Publicado no: | J Phys Chem B |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6010065/ https://ncbi.nlm.nih.gov/pubmed/22472179 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp300539j |
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