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Hypervalent iodine(III)-mediated decarboxylative acetoxylation at tertiary and benzylic carbon centers
The decarboxylative acetoxylation of carboxylic acids using a combination of PhI(OAc)(2) and I(2) in a CH(2)Cl(2)/AcOH mixed solvent is reported. The reaction was successfully applied to two types of carboxylic acids containing an α-quaternary and a benzylic carbon center under mild reaction conditi...
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| Publicado no: | Beilstein J Org Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6009488/ https://ncbi.nlm.nih.gov/pubmed/29977378 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.14.92 |
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