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Cyanide-bridged iron complexes as biomimetics of tri-iron arrangements in maturases of the H cluster of the di-iron hydrogenase
Developing from certain catalytic processes required for ancient life forms, the H(2) processing enzymes [NiFe]- and [FeFe]-hydrogenase (H(2)ase) have active sites that are organometallic in composition, possessing carbon monoxide and cyanide as ligands. Simple synthetic analogues of the 2Fe portion...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
Royal Society of Chemistry
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6008931/ https://ncbi.nlm.nih.gov/pubmed/30009000 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00213g |
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