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Stereo- and Regiocontrolled Methylboration of Terminal Alkynes
[Image: see text] A scalable and operationally simple synthesis of trisubstituted alkenyl boronic esters has been achieved using a Zr-catalyzed carboalumination of terminal alkynes followed by in situ transmetalation with i-PrOBpin. The products are formed in good yields and with excellent regiosele...
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| Publicado no: | Org Lett |
|---|---|
| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2018
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6007961/ https://ncbi.nlm.nih.gov/pubmed/29741904 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b01252 |
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