Evaluation of the coordination preferences and catalytic pathways of heteroaxial cobalt oximes towards hydrogen generation

Three new heteroaxial cobalt oxime catalysts, namely [Co(III)(prdioxH)((4tBu)py)(Cl)]PF(6) (1), [Co(III)(prdioxH)((4Pyr)py)(Cl)]PF(6) (2), and [Co(III)(prdioxH)((4Bz)py)(Cl)]PF(6) (3) have been studied. These species contain chloro and substituted tert-butyl/pyrrolidine/benzoyl-pyridino ligands axia...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Basu, Debashis, Mazumder, Shivnath, Niklas, Jens, Baydoun, Habib, Wanniarachchi, Dakshika, Shi, Xuetao, Staples, Richard J., Poluektov, Oleg, Schlegel, H. Bernhard, Verani, Cláudio N.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6006490/
https://ncbi.nlm.nih.gov/pubmed/29997819
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc04214c
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