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Unimolecular reaction of acetone oxide and its reaction with water in the atmosphere

Criegee intermediates (i.e., carbonyl oxides with two radical sites) are known to be important atmospheric reagents; however, our knowledge of their reaction kinetics is still limited. Although experimental methods have been developed to directly measure the reaction rate constants of stabilized Cri...

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Pubblicato in:Proc Natl Acad Sci U S A
Autori principali: Long, Bo, Bao, Junwei Lucas, Truhlar, Donald G.
Natura: Artigo
Lingua:Inglês
Pubblicazione: National Academy of Sciences 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6004451/
https://ncbi.nlm.nih.gov/pubmed/29844185
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1804453115
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