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Stochastic Model of Unimolecular Reactions and the RRKM Theory

A stochastic model of unimolecular reactions has been adopted for investigation of the validity and limitation of the RRKM theory. The error caused by the steady-state approximation for distribution of energized molecules is small, while the assumption of the internal energy equilibration of energiz...

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Detalhes bibliográficos
Publicado no:Proc Natl Acad Sci U S A
Main Authors: Lin, S. H., Lau, K. H., Richardson, W., Volk, L., Eyring, H.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 1972
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389643/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592018/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.69.10.2778
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