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Synthesis and applications of highly functionalized 1-halo-3-substituted bicyclo[1.1.1]pentanes

Bicyclo[1.1.1]pentanes (BCPs) are important bioisosteres of 1,4-disubstituted arenes, tert-butyl and acetylenic groups that can impart physicochemical benefits on drug candidates. Here we describe the synthesis of BCPs bearing carbon and halogen substituents under exceptionally mild reaction conditi...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Caputo, Dimitri F. J., Arroniz, Carlos, Dürr, Alexander B., Mousseau, James J., Stepan, Antonia F., Mansfield, Steven J., Anderson, Edward A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6001403/
https://ncbi.nlm.nih.gov/pubmed/29997886
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01355a
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