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Unnatural Amino Acid Derivatives through Click Chemistry: Synthesis of Triazolylalanine Analogues

A novel tert-butyl 2-(1-oxoisolndolin-2-yl)acetate derivative is selectively alkylated with propargyl bromide in the presence of lithium hexamethyldisilazide. After removal of the tert-butyl protecting group, the resulting N-isoindolinyl (ethynylalanine) derivative is reacted with a series of azides...

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Bibliographic Details
Published in:Synlett
Main Authors: Patil, Pravin C., Luzzio, Frederick A.
Format: Artigo
Language:Inglês
Published: 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5997291/
https://ncbi.nlm.nih.gov/pubmed/29904233
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0036-1588510
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