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Cu-catalyzed enantioselective synthesis of tertiary benzylic copper complexes and their in situ addition to carbonyl compounds

Catalytic chemo- and enantioselective generation of tertiary benzylic copper complexes from Cu–B(pin) (pin = pinacolato) additions to 1,1-disubstituted alkenes followed by in situ reactions with ketones and carboxylic acid phenol esters to construct multifunctional alkylboron compounds that contain...

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Pubblicato in:Chem Sci
Autori principali: Cheng, Fengchang, Lu, Wenxin, Huang, Wei, Wen, Lu, Li, Mingfeng, Meng, Fanke
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5989696/
https://ncbi.nlm.nih.gov/pubmed/29938027
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00827b
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