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Testing the Push–Pull Hypothesis: Lewis Acid Augmented N(2) Activation at Iron
We present a systematic investigation of the structural and electronic changes that occur in an Fe(0)–N(2) unit (Fe(depe)(2)(N(2)); depe = 1,2-bis(diethylphosphino)-ethane) upon the addition of exogenous Lewis acids. Addition of neutral boranes, alkali metal cations, and an Fe(2+) complex increases...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5965694/ https://ncbi.nlm.nih.gov/pubmed/28414226 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01982 |
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