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Controlling the hydrogenolysis of silica-supported tungsten pentamethyl leads to a class of highly electron deficient partially alkylated metal hydrides
The well-defined single-site silica-supported tungsten complex [([triple bond, length as m-dash]Si–O–)W(Me)(5)], 1, is an excellent precatalyst for alkane metathesis. The unique structure of 1 allows the synthesis of unprecedented tungsten hydrido methyl surface complexes via a controlled hydrogenol...
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| Udgivet i: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5964938/ https://ncbi.nlm.nih.gov/pubmed/29899899 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03490f |
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