Well-defined silica supported aluminum hydride: another step towards the utopian single site dream?

Reaction of triisobutylaluminum with SBA15(700) at room temperature occurs by two parallel pathways involving either silanol or siloxane bridges. It leads to the formation of a well-defined bipodal [([triple bond, length as m-dash]SiO)(2)Al–CH(2)CH(CH(3))(2)] 1a, silicon isobutyl [[triple bond, leng...

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Bibliografische gegevens
Gepubliceerd in:Chem Sci
Hoofdauteurs: Werghi, Baraa, Bendjeriou-Sedjerari, Anissa, Sofack-Kreutzer, Julien, Jedidi, Abdesslem, Abou-Hamad, Edy, Cavallo, Luigi, Basset, Jean-Marie
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: Royal Society of Chemistry 2015
Onderwerpen:
Chemistry
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5505125/
https://ncbi.nlm.nih.gov/pubmed/28757945
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02276b
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