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Divergent Control of Point and Axial Stereogenicity: Catalytic Enantioselective C–N Bond-Forming Cross-Coupling and Catalyst-Controlled Atroposelective Cyclodehydration

Catalyst control over reactions that produce multiple stereoisomers is a challenge in synthesis. Control over reactions that involve stereogenic elements remote from one another is particularly uncommon. Additionally, catalytic reactions that address both stereogenic carbon and an element of axial c...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Kwon, Yongseok, Chinn, Alex J., Kim, Byoungmoo, Miller, Scott J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5964046/
https://ncbi.nlm.nih.gov/pubmed/29637680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201802963
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