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Ligand metathesis as rational strategy for the synthesis of cubane-type heteroleptic iron–sulfur clusters relevant to the FeMo cofactor
Molybdenum-dependent nitrogenases catalyze the transformation of dinitrogen into ammonia under ambient conditions. The active site (FeMo cofactor) is the structurally and electronically complex weak-field metal cluster [MoFe(7)S(9)C] built of Fe(4)S(3) and MoFe(3)S(3)C portions connected by three su...
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| Udgivet i: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5960317/ https://ncbi.nlm.nih.gov/pubmed/29654147 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1801025115 |
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