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Structurally characterized terminal manganese(iv) oxo tris(alkoxide) complex
A Mn(iv) complex featuring a terminal oxo ligand, [Mn(IV)(O)(ditox)(3)][K(15-C-5)(2)] (3; ditox = (t)Bu(2)MeCO(–), 15-C-5 = 15-crown-5-ether) has been isolated and structurally characterized. Treatment of the colorless precursor [Mn(II)(ditox)(3)][K(15-C-5)(2)] (2) with iodosobenzene affords 3 as a...
Shranjeno v:
| izdano v: | Chem Sci |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Royal Society of Chemistry
2018
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5958342/ https://ncbi.nlm.nih.gov/pubmed/29896395 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01164h |
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