Magnesium-catalysed nitrile hydroboration

A β-diketiminato n-butylmagnesium complex is presented as a selective precatalyst for the reductive hydroboration of organic nitriles with pinacolborane (HBpin). Stoichiometric reactivity studies indicate that catalytic turnover ensues through the generation of magnesium aldimido, aldimidoborate and...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Weetman, Catherine, Anker, Mathew D., Arrowsmith, Merle, Hill, Michael S., Kociok-Köhn, Gabriele, Liptrot, David J., Mahon, Mary F.
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2016
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5952893/
https://ncbi.nlm.nih.gov/pubmed/29896350
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03114a
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