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Enantiodivergent asymmetric catalysis with the tropos BIPHEP ligand and a proline derivative as chiral selector
A catalytic system based on the tropos ligand BIPHEP and (S)-proline methyl ester as chiral selector was studied for Rh-catalysed asymmetric catalysis. By careful control of the catalyst preformation conditions, the enantioselectivity could be completely reversed in asymmetric hydrogenation of proch...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5952544/ https://ncbi.nlm.nih.gov/pubmed/29861999 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03465e |
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