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Charge transfer and ultrafast nuclear motions: the complex structural dynamics of an electronically excited triamine

Three ionization centers make 1,3,5-trimethyl-1,3,5-triazacyclohexane (TMTAC) an interesting model system to study intramolecular charge transfer (CT). Because the molecule assumes a C(s) symmetric, axial–equatorial–equatorial (aee) conformation in the ground state, there are two distinct types of t...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Cheng, Xinxin, Gao, Yan, Rudakov, Fedor, Weber, Peter M.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5952542/
https://ncbi.nlm.nih.gov/pubmed/29861998
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03042k
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