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C–H arylation and alkenylation of imidazoles by nickel catalysis: solvent-accelerated imidazole C–H activation

The first nickel-catalyzed C–H arylations and alkenylations of imidazoles with phenol and enol derivatives are described. Under the influence of Ni(OTf)(2)/dcype/K(3)PO(4) (dcype: 1,2-bis(dicyclohexylphosphino)ethane) in t-amyl alcohol, imidazoles can undergo C–H arylation with phenol derivatives. T...

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Shranjeno v:
Bibliografske podrobnosti
izdano v:Chem Sci
Main Authors: Muto, Kei, Hatakeyama, Taito, Yamaguchi, Junichiro, Itami, Kenichiro
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2015
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5951105/
https://ncbi.nlm.nih.gov/pubmed/29861924
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02942b
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