Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes

Reactions of the solution stable, two-coordinate hydrido-tetrylenes, :E(H)(L(†)) (E = Ge or Sn; L(†) = –N(Ar(†))(SiPr(i)(3)); Ar(†) = C(6)H(2){C(H)Ph(2)}(2)Pr(i)-2,6,4), with a variety of unactivated cyclic and acyclic alkenes, and one internal alkyne, lead to the rapid and regiospecific hydrometall...

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Vydáno v:Chem Sci
Hlavní autoři: Hadlington, Terrance J., Hermann, Markus, Frenking, Gernot, Jones, Cameron
Médium: Artigo
Jazyk:Inglês
Vydáno: Royal Society of Chemistry 2015
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5950753/
https://ncbi.nlm.nih.gov/pubmed/29861960
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03376d
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