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Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes
Reactions of the solution stable, two-coordinate hydrido-tetrylenes, :E(H)(L(†)) (E = Ge or Sn; L(†) = –N(Ar(†))(SiPr(i)(3)); Ar(†) = C(6)H(2){C(H)Ph(2)}(2)Pr(i)-2,6,4), with a variety of unactivated cyclic and acyclic alkenes, and one internal alkyne, lead to the rapid and regiospecific hydrometall...
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| Опубликовано в: : | Chem Sci |
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| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
Royal Society of Chemistry
2015
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5950753/ https://ncbi.nlm.nih.gov/pubmed/29861960 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03376d |
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