Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La(2+) and Ce(2+) are four electron reductants

A new option for stabilizing unusual Ln(2+) ions has been identified in the reaction of Cp′(3)Ln, 1-Ln (Ln = La, Ce; Cp′ = C(5)H(4)SiMe(3)), with potassium graphite (KC(8)) in benzene in the presence of 2.2.2-cryptand. This generates [K(2.2.2-cryptand)](2)[(Cp′(2)Ln)(2)(μ-η(6):η(6)-C(6)H(6))], 2-Ln,...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Kotyk, Christopher M., Fieser, Megan E., Palumbo, Chad T., Ziller, Joseph W., Darago, Lucy E., Long, Jeffrey R., Furche, Filipp, Evans, William J.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5947538/
https://ncbi.nlm.nih.gov/pubmed/29861961
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02486b
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