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Chiral ion-pair organocatalyst promotes highly enantioselective 3-exo iodo-cycloetherification of allyl alcohols

By designing a novel chiral ion-pair organocatalyst composed of chiral phosphate and DABCO-derived quaternary ammonium, highly enantioselective 3-exo iodo-cycloetherification of allyl alcohols was achieved using NIS as a halogen source. Based on this reaction, one-pot asymmetric 3-exo iodo-cycloethe...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Shen, Zhigao, Pan, Xixian, Lai, Yisheng, Hu, Jiadong, Wan, Xiaolong, Li, Xiaoge, Zhang, Hui, Xie, Weiqing
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5947518/
https://ncbi.nlm.nih.gov/pubmed/29861937
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02485d
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