Non-decarbonylative photochemical versus thermal activation of Bu(4)N[Fe(CO)(3)(NO)] – the Fe-catalyzed Cloke–Wilson rearrangement of vinyl and arylcyclopropanes

The base metal complex Bu(4)N[Fe(CO)(3)(NO)] (TBA[Fe]) catalyzes the rearrangement of vinyl and arylcyclopropanes both under thermal or photochemical conditions to give the corresponding vinyl or aryldihydrofurans in good to excellent yields. Under photochemical conditions the reaction is performed...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chem Sci
Egile Nagusiak: Lin, Che-Hung, Pursley, Dominik, Klein, Johannes E. M. N., Teske, Johannes, Allen, Jennifer A., Rami, Fabian, Köhn, Andreas, Plietker, Bernd
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Royal Society of Chemistry 2015
Gaiak:
Chemistry
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5947516/
https://ncbi.nlm.nih.gov/pubmed/29861942
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02342d
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