Non-decarbonylative photochemical versus thermal activation of Bu(4)N[Fe(CO)(3)(NO)] – the Fe-catalyzed Cloke–Wilson rearrangement of vinyl and arylcyclopropanes

The base metal complex Bu(4)N[Fe(CO)(3)(NO)] (TBA[Fe]) catalyzes the rearrangement of vinyl and arylcyclopropanes both under thermal or photochemical conditions to give the corresponding vinyl or aryldihydrofurans in good to excellent yields. Under photochemical conditions the reaction is performed...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Lin, Che-Hung, Pursley, Dominik, Klein, Johannes E. M. N., Teske, Johannes, Allen, Jennifer A., Rami, Fabian, Köhn, Andreas, Plietker, Bernd
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5947516/
https://ncbi.nlm.nih.gov/pubmed/29861942
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02342d
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