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Pd(ii)-catalyzed synthesis of bifunctionalized carboranes via cage B–H activation of 1-CH(2)NH(2)-o-carboranes

Aminoalkyl carboranes are anticipated to be valuable synthons toward the synthesis of bifunctionalized carboranes. However, direct cage boron derivation of these carborane derivatives has not been solved. Herein, the reversible conversion of catalytically infeasible o-carboranyl methylamines (1-CH(2...

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Библиографические подробности
Опубликовано в: :Chem Sci
Главные авторы: Zhang, Xiaolei, Yan, Hong
Формат: Artigo
Язык:Inglês
Опубликовано: Royal Society of Chemistry 2018
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC5941203/
https://ncbi.nlm.nih.gov/pubmed/29780529
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc01154k
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